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Showing 1 to 3 of 3 for “"Iodonium salt"”.
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Chemical Methods for Cobalt-Catalysed C(sp3)–H Activation and Iodonium Salt-Mediated Peptide Functionalisation
… the development of a rapid, room-temperature iodonium-salt mediated arylation procedure of hydroxylamines to afford N-oxide products is described. This approach has been applied to the metal-free, room temperature synthesis of substituted anilines. A diverse range of aromatic groups, including …
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Towards the Development, Application and Understanding of Copper-Catalysed Alkene Functionalisation Processes Using Iodonium Salts
… use of the combination of catalytic copper and iodonium salts towards the functionalisation of alkenes. Chapter 2 details the development of an enantioselective and regiodivergent allylic amide arylation procedure using a specific copper(II)-bisoxazoline pre-catalyst and hexafluorophosphate …
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Selective Protein Functionalisation at Methionine
… iodine reagents, varying the ester group of the iodonium salt (R), a number of different payloads can be transferred to polypeptides and proteins. The highly reactive diazo group which is introduced using this methodology can be exploited in subsequent bioorthogonal transformations. Firstly, …