Global ETD Search
Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
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Showing 1 to 11 of 11 for “"Inorganic Synthesis"”.
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Polyelectrolyte multilayers as nanostructured templates for inorganic synthesis
Thin film nanocomposites consisting of inorganic matter embedded within a soft polymeric matrix on the nanometer length scale are an important class of materials with potential application in optoelectronics and photonics, magnetic media, and batteries and fuel cells. In addition to the component …
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Machine Learning Enabled Inorganic Synthesis Planning and Materials Design
… and computing technology. Data-driven synthesis planning with machine learning is a key step in the design of novel inorganic compounds with desirable properties. Inorganic materials synthesis is often guided by heuristics and chemists' prior knowledge and experience, built upon …
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Genetic engineering of bacteriophage and its applications for biomimetic materials
… method in non-biological conditions for inorganic synthesis was introduced.
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The Interplay Between Anions And Radicals In Synthesis, Spectroscopy, And Catalysis
… than previously proposed. Next, our successful synthesis and isolation of a compound containing a CeIV–Caryl bond enabled the investigation of the complex by 13C NMR and computation. These studies determined that the CeIV–Caryl bond displayed significant covalency. The use of the TiCl62- dianion …
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Modeling metallo-oxidoreductase active site dynamics with bis(μ-hydroxo)dicobalt complexes
Submission published under a 24 month embargo labeled 'U of I Access', the embargo will last until 2025-12-01
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Tris-Pyridyl Ligands and Beyond: Modifications Derived from the Bridgehead and Donor Vector
… coordination and supramolecular chemistry using inorganic frameworks, and this thesis is focused on fundamental research in the synthesis and design of ligand molecules of this type. In Chapter 1, a concise account of previous studies of tris 2-, 3- and 4-pyridyl based ligands E(py)3 (where E = a …
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Synthetic Applications of Polar Transition Metal Metallocenes
… halide starting materials for organometallic synthesis is much more common due to their being readily commercially available and generally easier to handle than the extremely air- and moisture-sensitive metallocene alternatives. In this project, the polar transition metal metallocenes Cp2V, …
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Volatile metal borohydride complexes: synthesis and characterization of new chemical vapor deposition precursors
… 250 and 350 °C using this new precursor. The synthesis of sodium aminodiboranates with sterically bulky or electron withdrawing substituents on nitrogen has been achieved by the treating amine-borane with either BH3•THF or by thermolysis at elevated temperatures followed by the addition of …
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Amorphous calcium phosphate nanoparticles for biomedical cargo delivery
… These findings subsequently informed the synthesis of functionalised ACP nanoparticles via an impinging jet reactor that I developed for this purpose. Particle size was tuneable, varying with reactor parameters, particularly flow rate and impingement angle. Surface chemistry could also be …
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A study of the synthesis, structure, and ionic conductivity of sodium and lithium lanthanide pyrosilicates, A3LnSi2O7
In this thesis the synthesis, structure, and ionic conductivity of the sodium and lithium lanthanide pyrosilicates, A3LnSi2O7 (A = Li, Na; Ln = Gd-Er, Y), are reported. The Na- silicates, Na3LnSi2O7, were made by the ceramic method. The meta-stable Li-silicates, Li3LnSi2O7, were formed by a molten …