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Showing 1 to 2 of 2 for “"Homoallyl-Verbindungen"”.
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Asymmetrische Synthese und stereoselektive Substitution allylischer Sulfoximin-funktionalisierter Homoallylalkohole
… afforded the corresponding alpha-syn-configured homoallylic alcohols with moderate to high regioselectivities and high diastereoselectivities. Copper-mediated subtitution in gamma position of the sulfonimidoyl-group furnished the corresponding (E)-configured allylic alcohols in good yields, with …
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Asymmetrische Synthese funktionalisierter Homoallyl- und Homopropargylalkohole mittels der Sulfoximin-Route
… the sulfoximine-route by Gais et al. new chiral homoallyllic alcohols were synthesized. Elimination of the sulfoximine-group lead to optically pure homopropargylic alcohols. Via Nickel-catalysed cross-coupling reactions (homogenoes and heterogenoes Catalysis) of the homoallylic alcohols …