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Showing 1 to 2 of 2 for “"Hiyama Coupling"”.

  1. Part I. Approaches Toward the Total Synthesis of Tyloindicine F; Part II. Palladium-Catalyzed C−H Functionalization of β-enaminones

    … olefins whereas C-H functionalization/C-C coupling is a highly efficient method of constructing new carbon-carbon bonds. β-enaminones are highly polarized and their β; position is suitable for C-H functionalization by means of electropalladation. A novel methodology for the oxidative Hiyama

    ku Repository record for Part I. Approaches Toward the Total Synthesis of Tyloindicine F; Part II. Palladium-Catalyzed C−H Functionalization of β-enaminones (opens in a new tab)

  2. Investigation of aryldimethylsilanolates in palladium-catalyzed cross-coupling reactions and development of chiral bis-hydrazone ligands for asymmetric aryl-aryl couplings

    … of biaryls by palladium-catalyzed cross-coupling of aromatic bromides and chlorides with alkali-metal salts (potassium and sodium) of aryl- and heteroarylsilanols has been developed. The critical feature for the success of this method is the use of bis(tri-tert-butylphosphine)palladium …

    uiuc Repository record for Investigation of aryldimethylsilanolates in palladium-catalyzed cross-coupling reactions and development of chiral bis-hydrazone ligands for asymmetric aryl-aryl couplings (opens in a new tab)