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Showing 1 to 1 of 1 for “"High-Valent Metal Oxos"”.
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Kinetic and Spectroscopic Investigation of Structural Influences on Hydrogen-atom Transfer Reactivity of N5-Ligated Oxomanganese(IV) Complexes
High valent iron- and manganese-oxo intermediates perform important hydrogenatom transfer (HAT) reactions in both biological and synthetic systems. There has been extensive characterization of HAT reactivity of enzymatic and synthetic oxoiron(IV) species, and these complexes have been shown to …