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Showing 1 to 1 of 1 for “"Heterocyclische Carbene <-N>"”.
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Entwicklung von Carben-katalysierten asymmetrischen intermolekularen Stetter-Reaktionen und direkt gekreuzter intermolekularer Benzoin-Reaktionen
A new chiral triazolium based carbene precatalyst was synthesized and successfully employed in the asymmetric intermolecular Stetter reaction. The resulting 1,4-diketones were obtained in moderate to excellent yields (49-98%) and good enantioselectivities (56-78% ee). For several Stetter products …