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Showing 1 to 2 of 2 for “"Halfsandwich-complexes"”.
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Organometallic and coordination chemistry of (Tetramethylcyclobutadiene)cobalt sandwich and halfsandwich complexes
… (Cb*Co) tris(ligand) complexes [Cb*Co(L)3]+. An improved synthesis of the starting materials [Cb*Co(CO)3]BF4, Cb*CoI(CO)2 and [Cb*Co(C6H6)]PF6 was developed. Photolysis of [Cb*Co(C6H6)]PF6 in acetonitrile produced [Cb*Co(NCMe)3]PF6. Alternatively, the tris(acetonitrile) …
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Halfsandwich tungsten complexes with a silanol-functionalized cyclopentadienyl ligand : synthesis and reactivity
Within the studies concerning metallo-silanols, halfsandwich-tungsten complexes have been silanol-functionalized at the cyclopentadienyl ligand. The stability and the condensation behavior have been investigated. Thus, it was shown that these complexes are stable enough for isolation but they are …