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Showing 1 to 7 of 7 for “"Half-sandwich complexes"”.
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Metal complexes with ligand-tethered organo-hydride donor groups - new prospects for efficient multi-electron reduction
… NADPH, set out to explore the potential of metal complexes with a ligand-tethered OHD or OHD conjugate cation group as new, efficient and green catalysts for the reduction of unsaturated substrates. A myriad of such complexes substituted by nicotinamide, Hantszch ester and benzimidazole groups …
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Advances in medicinal inorganic chemistry: Exploiting the biological activity of metal arene complexes
Half-sandwich complexes containing transition metals offer a wide range of applications owing to their interactions with a variety of targets/molecules that are not accessible for some organic scaffolds. The use of such complexes is therefore a way to provide new mechanisms of action. In this …
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Advances in medicinal inorganic chemistry: Exploiting the biological activity of metal arene complexes
Half-sandwich complexes containing transition metals offer a wide range of applications owing to their interactions with a variety of targets/molecules that are not accessible for some organic scaffolds. The use of such complexes is therefore a way to provide new mechanisms of action. In this …
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The Development of New Routes to Half-Sandwich Metallatricarbadecaborane Complexes, Triflate-Functionalized Polyboranes and Carboranes, and Ammonia Borane Hydrogen Release
… and characterize the first extensive series of half-sandwich metallatricarbadecaborane complexes, (2) to synthesize and explore the reactivity of 5-TfO-B10H13, and (3) to investigate metal-catalyzed hydrogen release from ammonia borane in ionic liquids. The major achievements are outlined below. …
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Tripodal Inorganic 2-Pyridyl-phosphine Ligands and Unsymmetrical Analogues: Towards New Applications in Catalysis
… Whereas P(2-py)3 readily forms the cationic sandwich complex [{P(2-py)3}2Fe]2+, P(6-Me-2-py)3 forms only half-sandwich complexes of the type [{P(6-Me-2-py)3}FeX2] (X = Cl, OTf). In addition to C3-symmetric ligands, a range of unsymmetrical multidentate 2-pyridyl-phosphine ligands with …
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Neutral and cationic complexes of the rare earth metals : synthesis, characterisation and polymerisation catalysis
… starting materials for the access to cationic complexes of the rare-earth metals are the homoleptic tris(trimethylsilylmethyl) precursors [Ln(CH2SiMe3)3(thf)2]. The principal objective of this work has been to substitute the well-known CH2SiMe3 group for other fragments, and study the …