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Showing 1 to 2 of 2 for “"Germene"”.
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Doubly Bonded Derivatives of Si and Ge: Cycloaddition Reactions and Polymer Chemistry
… OCH3, and R3P:,where R = OCH3,to tetramesityldigermene 1.2 and/or the germene 1.1 is reported in an effort to give a broader understanding of the chemistry of the addition of phosphine oxides to (di)tetrelenes. In general, a 1,2-adduct is formed which appears to be derived from the isomeric …
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Cycloaddition Reactions of (Di)tetrelenes
… the mechanism of the addition of alkynes to a germene and a digermyne was examined. In both cases, the addition does not involve the itermediacy of an vinyl radicals or cations. The addition of a variety of nitro compounds to tetramesityldisilene and tetramesityldigermene was examined. The …