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SYNTHESIS OF N-HETEROCYCLES VIA PALLADIUM-CATALYZED REDUCTIVE CYCLIZATION REACTIONS OF NITROARENES AND NITROALKENES USING FORMIC ACID DERIVATIVES AS CO SURROGATES

ABDELLATIF, MANAR AHMED FOUADUniversità degli Studi di Milano2024

… Thus, the thesis focuses on the use of phenyl formate and ‎formic acid as cheap, affordable, efficient and safe in-situ CO surrogates for the reductive ‎cyclization of various nitroarenes. Notably, in most cases, the isolated yield of the desired ‎heterocycle was higher than those previously …

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