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Showing 1 to 2 of 2 for “"Fluorinated Amines"”.
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Synthetic studies of sodium aminodiboranate salts with electronwithdrawing substituents
… In chapter 2 we describe the preparation of fluorinated aminodiborantes, although here the longer reaction times required for their synthesis lead to undesirable production of butoxyborate species through the ring-opening reaction of thf with BH3. To circumvent this problem, we employed …
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Fluorination of Rubisco-Mimetic CO2 Capture Systems. Theoretical and Experimental Studies of Ammonium Ion Acidity Depression and Carbamylation
… capture and release (CCR) systems featuring amines have been developed for the purpose of reversable CO<sub>2</sub> capture from air. The enzyme active site consists of the tetrapeptide sequence Lys-Asp-Asp-Glu. The Lys sidechain amine undergoes carbamylation and an Mg<sup>2+</sup> cation …