Global ETD Search
Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
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Showing 1 to 7 of 7 for “"First-row transition metal complexes"”.
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Bio-inspired first-row transition metal complexes for small molecule activation
… important roles in the activity and function of metalloenzymes: they can help stabilize reactive intermediates and shuttle protons or electrons over the course of enzymatic transformations. Accordingly, there have been numerous efforts to mimic these advantageous structural and functional …
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Activation of small oxygen containing molecules by bioinspired first row transition metal complexes
Submission published under a 24 month embargo labeled 'U of I Access', the embargo will last until 2026-05-01
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Sharing the Burden of Reactivity: Synthesis, Characterization, and Reactivity of Phosphino-Alkoxide First-Row Transition Metal Complexes
… and petrochemical production, use precious metals to perform critical synthetic transformations that rely on bond activation. Due to the scarce nature of these precious metals, alternative approaches to bond activation have been sought. One such alternative approach is the polarization of …
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Design and synthesis of new metallo-organic complexes and their evaluation as anti-cancer agents. Synthesis, characterisation and biological evaluation of novel, late first row transition metal schiff base complexes, as anti-cancer metallopharmaceuticals
… with the design and synthesis of the cheap, late first row transition metal complexes of Schiff base ligand systems. The prepared complexes readily afford systematic variation in order to probe potency and understand the role of metal, chelating ligands and anionic ligands when carrying out their …
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The catalytic hydrogenation of carbon-carbon and carbon-nitrogen multiple bonds by a cobalt(I) complex
… use of homogenous late second- and third-row transition metal complexes for the catalytic hydrogenation of carbon-carbon multiple bonds can be attributed to the well-defined reactivity, stability and overall high activity of such catalytic systems. The development of sustainable, more …
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Exploring Molecular Systems From Chemical Physics To Biochemistry Using Classical And Quantum Mechanics
… intensities of some organic molecules and simple first row transition metal complexes. Choice of a reasonable basis set seemed to have little effect on the calculated electronic spectra of the inorganic complexes. Long-range corrected functionals and hybrid density functionals seemed to perform …