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Showing 1 to 3 of 3 for “"Fe(IV)oxo"”.
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Density Functional Studies of the Structure, Properties and Applications of Copper and Iron Complexes of 3,7-Diazabicyclo[3.3.1]nonane Derivatives
Die 3,7-Diazabicyclo[3.3.1]nonan (Bispidin) Derivate verfügen über ein starres Ligandgerüst, weisen jedoch eine elastische Koordinationssphäre auf. Daher sind sie in der Lage, eine Reihe verschiedener Übergansmetalle zu komplexieren, wobei spezifische Geometrien für die entsprechenden …
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Development of solution-phase extreme ultraviolet spectroscopy and photophysics of μ-oxo-bridged Fe(III)porphyrins
A sample delivery method is developed to extend the field of transient M-edge x-ray absorption spectroscopy to study molecular complexes in the solution-phase. A gas-accelerated liquid sheet method is adapted to operate in the vacuum conditions needed for XUV transmission. Gas-generated liquid …
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Ligand field considerations for the reactivity of high valent metal-oxo complexes and of bimetallic HX splitting photocatalysts
… the O-O bond formation process, terminal metal oxo complexes of pseudotetrahedral geometry were synthesized and studies focused on determining the electronic structure of these complexes as well as reactivity patterns. A novel series of low coordinate tris(alkoxide) complexes of divalent and …