Global ETD Search

Molybdenum and tungsen alkylidene species for catalytic Enantio-, Z-, and E-selective olefin metathesis reactions

Marinescu, Smaranda ConstanţaMassachusetts Institute of Technology2011

… aryloxide ligand are efficient for ethenolysis of methyl oleate, cyclooctene, and cyclopentene. Ethenolysis of 5000 equivalents of methyl oleate produced 1- decene (1D) and methyl-9-decenoate (M9D) with a selectivity of >99%, yields up to 95%, and a TON (turnover number) of 4750 in …

mit Repository record for Molybdenum and tungsen alkylidene species for catalytic Enantio-, Z-, and E-selective olefin metathesis reactions (opens in a new tab)

Development and Application of N-Trifluoromethyl NHC Ligands for Transition-Metal Catalysis

Engl, Pascal StephanETH Zurich2017

ethz Repository record for Development and Application of N-Trifluoromethyl NHC Ligands for Transition-Metal Catalysis (opens in a new tab)

Selective deconstruction of polyethylene to propylene via isomerization/metathesis and 1-hexene isomerization studies

DaSilva, VanessaUniversity of Illinois Urbana-Champaign2025

Polyethylene (PE), the world’s most produced single-use plastic, poses a significant environmental challenge due to its chemical inertness and resistance to degradation. Traditional recycling approaches—mechanical recycling and incineration—fail to offer selective, and circular solutions for …

uiuc Repository record for Selective deconstruction of polyethylene to propylene via isomerization/metathesis and 1-hexene isomerization studies (opens in a new tab)