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Showing 1 to 2 of 2 for “"Epiibogamine"”.
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METHODOLOGY DEVELOPMENT OF N-SULFINYL METALLOENAMINES AND ASYMMETRIC TOTAL SYNTHESIS OF (+)-EPIIBOGAMINE
… methodologies toward the total syntheses of (+)-epiibogamine and (+)-chimonanthine is described. The vinylogous aldol reaction of N-sulfinyl metallodienamines was first reported in 2017 in the total synthesis of (−)-albocycline. However, the diastereoselectivity of this reaction was found to be …
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NATURAL PRODUCT INSPIRED METHODOLOGIES: ADVANCES IN DIASTEREOSELECTIVE N-SULFINYL IMINE AND TRIFLUOROPYRUVIC ACID REACTIONS
… reaction for the concise total synthesis of (+)- epiibogamine. The domino reaction enabled us to set all the stereocenters in the natural product in a single step with high diastereoselectivity enabling access to the natural product in a concise 7 steps. I also worked briefly on developing …