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Showing 1 to 1 of 1 for “"Enantiotopic group&face selective"”.
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Chemistry with chiral lithium amides: enantiotopic group and face-selective reactions
… from β-keto esters of tropinone and the enantioselective aziridine formation from nortropinone is first reported. This opened two new paths to develop tropinone enolate chemistry. One is indirect α-alkylation of tropinone, another is the nucleophilic attack from α-C enolate to the nitrogen atom. …