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Showing 1 to 2 of 2 for “"Diterpenes--Synthesis"”.
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Part I. Total Synthesis and Structural Revision of (±)-Tricholomalides A and B. Part II. Synthetic Studies towards (+)-Cortistatin A
The first part describes the total synthesis and structural revision of (±)-tricholomalides A and B. The synthetic strategy started from a homo-Robinson annulation, followed by a ketene-olefin [2+2] cycloaddition to introduce the lactone ring. Then a Grignard-type reaction appended the isopropenyl …
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A Concise, Stereocontrolled Total Synthesis of Rippertenol
Rippertenol and the kempane diterpenes are biogenetically derived from cembrene A and are dense with stereochemical complexity despite a paucity of heteroatom functionality. A discussion of past synthetic efforts towards these complex targets is presented to define the current level of …