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Showing 1 to 3 of 3 for “"Digermene"”.
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Neue Reaktionsweisen eines Tetragermabuta-1,3-diens und von Digermenen
… with gold(I) iodide at 60 C furnished the first digermene-gold(I)-pi-complex. However, the analogous reaction of the correspondingly substituted digermene yielded solely a 1,2-diiododigermane, even at very low temperature.
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Cycloaddition Reactions of (Di)tetrelenes
… to tetramesityldisilene and tetramesityldigermene was examined. The facile formation of the novel 1,3,2,4,5-dioxazadisil- and digermolidine ring systems, respectively, was observed. In general, 1,3,2,4,5-dioxazadisilolidines and -digermolidines isomerize under thermal conditions to the …
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The Reactivity of Ditetrelenes Towards Organophosphorus Oxides
… of tetramesityldisilene 4 and tetramesityldigermene 5 towards organophosphorus oxides was explored in this thesis. The reaction of dialkyl and diarylphosphine oxides and phosphites with ditetrelenes 4 and 5 resulted in a 1,3-addition to form diorganodisilyl and digermyl phosphinites 27, 28, …