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Showing 1 to 4 of 4 for “"Diels-Alder polymerization"”.
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Studies Toward Highly Fluorinated Polyphenylenes by Diels-Alder Polymerization
Diels-Alder polyphenylenes (DAPPs) are chemically and thermally stable polymers, used for dielectric resins, gas separation membranes, and fuel cell proton exchange membranes. Highly fluorinated DAPPs are expected to have better thermal stability and chemical resistance, higher glass transition …
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Manipulation of ring strain and antiaromaticity in the design and synthesis of unique optoelectronic materials
… as a building block for sequential Diels-Alder reactions is described. The electronic effects of strain and the energetic cost of antiaromaticity can be observed via the optical and electrochemical properties of the reported compounds. The resulting shape-persistant ladder structures …
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Perfluoroarylated Cyclopentadienones: Synthesis, Characterization and Polymerization
… reports the synthesis of highly fluorinated Diels-Alder polyphenylenes. The first section of this chapter describes the three-pot synthesis of a perfluoroarylated bis(cyclopentadienone) monomer. The synthesis begins with the previously reported substitution reaction of decafluorobiphenyl and …
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Segmented Aromatic Polymers Containing Thermally Reversible Linkages
… linkages based on cyclopentadiene-maleimide Diels-Alder chemistry. Research in the area of thermally reversible (self-healing) polymers has been an ever-expanding area of interest in the current scientific literature. However most of the emphasis has been on systems containing furan-maleimide …