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Showing 1 to 2 of 2 for “"Diazosulfones"”.
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Synthesis and reactivity of α-diazosulfoxides and α-diazosulfones
… the synthesis of related mono and bicyclic α-diazosulfones were also undertaken, in both batch and flow. The α-diazosulfoxides are known to react via a hetero-Wolff rearrangement to form α-oxo sulfines. The 1,3-dipolar cycloadditions of these α-oxo sulfines were investigated further under Rh …
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Catalyst and substrate effects in enantioselective C–H insertion reactions of α-diazosulfones
… as fused cyclopropanes. The synthesis of the α-diazosulfones required for subsequent investigations is initially described. Of the twenty seven diazo sulfones described, nineteen are novel and are fully characterised in this work. The discussion is subsequently focused on a study of the copper …