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A study of some carbanions derived from organic halogen compounds. Part I, The reaction of b̲e̲t̲a̲-haloethyl bromides with sodium hydroxide; Part II, The base catalysed dehydrohalogenation of b̲e̲t̲a̲-benzene hexachloride

Langford, Paul BrooksGeorgia Institute of Technology1962

gatech Repository record for A study of some carbanions derived from organic halogen compounds. Part I, The reaction of b̲e̲t̲a̲-haloethyl bromides with sodium hydroxide; Part II, The base catalysed dehydrohalogenation of b̲e̲t̲a̲-benzene hexachloride (opens in a new tab)

Dipyrazolylphosphanes in Condensation and P–N/P–P Bond Metathesis Reactions

Schoemaker, RobinTechnische Universität Dresden

… dehalostannylation16 reactions, base promoted dehydrohalogenation reactions17 and dehydrogenative coupling reactions mediated by main group compounds18 or catalysis by transition metals.5,19 Moreover, dialkylamino-substituted phosphanes are used in condensation reactions to form P–P bonds since …

qucosa-diss

Synthetic studies on prostaglandins: "synthesis of a new thia-PGEI analog"

Ratemi, Elaref S.Brock University1992

… to ethynyl n.pentyl sulfide 81 is via a double dehydrohalogenation of the corresponding 1,2-dibromoethyl sulfide with sodium amide in liquid ammonia. In addition, the isomerically pure E-2-iodoethenyl n.pentyl sulfide 85 is conveniently prepared in high yield and stereoselectivity by …

brock Repository record for Synthetic studies on prostaglandins: "synthesis of a new thia-PGEI analog" (opens in a new tab)

Synthetic approaches to new three coordinate Group 6 compounds : chromium alkenyls, molybdenum thiolates and tungsten amides

Greco, Jane Brock, 1973-Massachusetts Institute of Technology2001

… ligands are synthesized by bromination and dehydrohalogenation of an adamantyl olefin to yield an alkenyl bromide. The Grignard reagent, derived from the bromide, is used either as a transmetallation reagent, or reacted with elemental sulfur to form a magnesium thiolate, (THF)2Mg(SC[Ad]Ar)2. …

mit Repository record for Synthetic approaches to new three coordinate Group 6 compounds : chromium alkenyls, molybdenum thiolates and tungsten amides (opens in a new tab)

Synthesis and reactivity of some β-substituted alkylphosphonates

Pearce, Madeleine AnneDepartment of Chemistry1986

… have been achieved, since once again the dehydrohalogenation product predominates. During an attempted synthesis of diethyl 2-iodopentylphosphonate by reaction of diethyl 2-chloropentylphosphonate with NaI, an unusual interaction between the sodium cation and the substrate in acetone …

cape-town Repository record for Synthesis and reactivity of some β-substituted alkylphosphonates (opens in a new tab)

Synthesis and Reactivity of Phosphorus-Containing Heterocycles and Tetrahedranes

Riu, Martin-Louis Y.Massachusetts Institute of Technology2022

… (ᵗBuC)₃P was prepared via the dehydrohalogenation of fluorophosphine (ᵗBuC)₃P(F)H. The phosphatetrahedrane core was confirmed spectroscopically and by X-ray diffraction analysis. Hydrogen-hydrogen bonding interactions between neighboring tert-butyl groups of (ᵗBuC)₃P were …

mit Repository record for Synthesis and Reactivity of Phosphorus-Containing Heterocycles and Tetrahedranes (opens in a new tab)

The Preparation of Amino Acids From 3,6-bis-(β-Chloroethyl)-2,5-Diketopiperazine

Chiddix, Max EugeneUniversity of Illinois at Urbana-Champaign1943

uiuc Repository record for The Preparation of Amino Acids From 3,6-bis-(β-Chloroethyl)-2,5-Diketopiperazine (opens in a new tab)