Global ETD Search
Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
Results
Showing 1 to 10 of 10 for “"Debye-Huckel"”.
-
Prediction of electrolyte solution properties using a combined Debye-Huckel, association and solvation model
… long-range electrostatic ion-ion interaction (Debye- Hückel effects), short-range ion-ion interactions (ion association), and short-range ion-solvent interactions (hydration). The activity of water in NaCl, NaOH, and HCl solutions is fit with maximum deviations from experimental values of …
-
Nonideality of Single and Mixed Electrolyte Solutions Up to Moderately High Concentration; Theory Based on Debye-Huckel Radial Distribution Function
Because of the complex nature of the solvent effect and of the mathematical difficulty in the treatment of the Coulombic long-range force, the theoretical treatments of the equilibrium properties of the electrolyte solution are not fully developed if one compares with those of the non-electrolyte …
-
Free solution electrophoresis measurements and their theoretical relationships to net protein valence
… this work compares the model predictions of Debye-Huckel-Henry (DHH), Booth, and the more recent boundary element (BE) modeling by Allison with experimental results.</p><p>The electrophoretic behavior of a macroion is affected in a complex manner by a variety of forces which arise from the …
-
The Partial Pressure of Hydrogen Chloride Above its Solutions in BB Dichloroethyl Ether and Anisole and the Calculation of the Heat and Entropy of Solution
… concerning non-aqueous solutions. However the Debye-Huckel theory of interionic attraction inspired such widespread study of many different solvents that today we have some understanding of the behavior of dilute aqueous solutions and of some extremely dilute non-aqueous solutions. |Another …
-
Valence and structure relationships in oligonucleotides
… valence of several nucleic acid oligomers. The Debye-Huckel-Henry equation was then utilized to calculate the valence of these oligomers. The valence was determined to be -17.86 (+/- 1.03) for a 20 base-pair double-stranded DNA oligomer in 93 mM KCl and 10 mM Tris HCl, pH 8. This experimental …
-
Conformation and Rheology of Semiflexible Macromolecules Using Non-Equilibrium Brownian Dynamics and Monte Carlo Simulations
… forces, and for polyelectrolytes a screened Debye-Huckel potential is also present. The Fokker-Planck equation describing this chain is converted to a Stochastic Differential Equation (SDE) from which the simulation algorithm for the NEBD is obtained. In steady, potential flows, the solution …
-
The Partial Pressure of Hydrogen Chloride Above its Solutions in Non-Aqueous Solvents, in Monohalobenzene Solutions
… the Bronsted concept of acids and bases and the Debye-Huckel theory of electrolytes, the study of chemical reactions in solution has been extended to reactions that take place in non-aqueous solvents. |In predicting the behavior of substances dissolved in a certain solvent it is necessary that …
-
Analysis of nucleation kinetics in pH-shift crystallization using agitated and microfluidic systems
… component and applying the Davies extension of Debye-Huckel theory. This model was vital for designing experiments as it was not always possible to directly measure solution pH.Nucleation rates were estimated by fitting induction time data collected isothermally, under relevant conditions, to a …
-
COMPUTATIONAL MULTISCALE INVESTIGATIONS OF BIOLOGICAL MOLECULES
… representation in implicit solvent employing Debye-Huckel electrostatics, and three different applications of the CANVAS model. The latter is a model multi-resolution for proteins, developed in my group, which combines atomistic force fields together with an elastic network model to describe …