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Showing 1 to 2 of 2 for “"Daphenylline"”.

  1. Approaches Towards a Total Synthesis of Daphenylline

    … synthesis of advanced intermediates enroute to daphenylline. Construction of the ABCE tetracyclic skeleton of daphenylline was accomplished in thirteen steps with seven percent overall yield from commercially available (S)-carvone through [3,3]-allyl cyanate-to-isocyanate rearrangement, …

    brock Repository record for Approaches Towards a Total Synthesis of Daphenylline (opens in a new tab)

  2. Chemoenzymatic Formal Total Syntheses of Tetrodotoxin and an Approach to Daphenylline

    … tetrodotoxin and a concise synthetic approach to daphenylline. Advanced intermediates for the syntheses of tetrodotoxin reported by the groups of Fukuyama, Alonso, and Sato were prepared. Key steps included toluene dioxygenase-mediated dihydroxylation of either iodobenzene or benzyl acetate and a …

    brock Repository record for Chemoenzymatic Formal Total Syntheses of Tetrodotoxin and an Approach to Daphenylline (opens in a new tab)