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Showing 1 to 5 of 5 for “"DMSO solutions"”.
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NMR Linebroadening and Contact Shift Studies of Transition Metal Complexes in Nonaqueous Solvents.
… nmr linebroadening studies of dimethylsulfoxide (DMSO) +3 in tris (ethylenediamine) chromium(III) (Cr(en)3 +3)-DMSO solutions were conducted between 20° and 90°C. The resulting data were interpreted using the Swift-Connick relationships. The dominant contribution to linebroadening in the …
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Binary diamondoid molecular gels
… gels are formed by mixing dimethyl sulfoxide (DMSO) solutions of 1-adamantanecarboxylic acid (A1C) with 1-adamantylamine (A1N). Upon mixing at vanishing concentrations, these diamondoid molecules rapidly aggregate. At approximately 3% by weight, the resulting suspension forms a percolated …
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Binding anions using simple neutral molecules
… a variety of oxo-anions in highly competitive DMSO solutions. Of these receptors, the diindolylurea motif was found to be excellent for the binding of dihydrogen phosphate. This group of receptors were found to form 1:1 complexes in solution with various anions but more complex 2:1 and 3:1 …
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Sistemas de Pt(II) y Pt(IV) basados en cromóforos 2-arilbenzotiazol: propiedades ópticas y aplicaciones biológicas
… cyclometalated derivatives. Labile groups (Cl, DMSO), cyanide, C6F5 and bioactive phosphines (having carboxilic o polyether units) have been used as auxiliary ligands to improve emission efficiencies or their solubility in biological media. Diferent oxidation reactions have been carried out …
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Electrically Polarised Electrodes in DMSO and DMF electrolytes of Pseudohalide Salts: In situ IR studies supported by EXAFS/XANES and other techniques
… dimethyl formamide (DMF) and dimethyl sulfoxide (DMSO) solutions, with a supporting electrolyte, tetrabutylammonium perchlorate (TBAP), is presented. Cyclic voltammograms, and current-potential data were recorded while the infrared spectral acquisition was in progress for nickel, copper and gold …