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Showing 1 to 7 of 7 for “"DIARYLIODONIUM SALTS"”.

  1. Chloro-arylation of Alkenes via Cooperative Photoredox and Atom-transfer Catalysis

    … diversity from readily available alkenes and diaryliodonium salts. The developed transformation benefits from a high degree of modularity through the independent functionalization of diaryliodonium salts and alkenes. In addition, broad functional group tolerance is observed under the mild …

    cambridge Repository record for Chloro-arylation of Alkenes via Cooperative Photoredox and Atom-transfer Catalysis (opens in a new tab)

  2. Applications of Hypervalent Iodine Reagents: From Enantioselective Copper-Catalysed Arylation-Semipinacol Cascade to Methionine Functionalisation for Peptide Macrocyclisation

    … exploitation of the reactivity of aryliodonium salts as electrophile transfer reagents. In the first part of the thesis, diaryliodonium salts are employed as arylation reagents for the enantioselective copper-catalysed arylative semipinacol rearrangement (SPR) of various tertiary allylic …

    cambridge Repository record for Applications of Hypervalent Iodine Reagents: From Enantioselective Copper-Catalysed Arylation-Semipinacol Cascade to Methionine Functionalisation for Peptide Macrocyclisation (opens in a new tab)

  3. Towards the Development, Application and Understanding of Copper-Catalysed Alkene Functionalisation Processes Using Iodonium Salts

    … the combination of catalytic copper and iodonium salts towards the functionalisation of alkenes. Chapter 2 details the development of an enantioselective and regiodivergent allylic amide arylation procedure using a specific copper(II)-bisoxazoline pre-catalyst and hexafluorophosphate …

    cambridge Repository record for Towards the Development, Application and Understanding of Copper-Catalysed Alkene Functionalisation Processes Using Iodonium Salts (opens in a new tab)

  4. Hypervalent iodine reagents for protein functionalisation

    … derivatives using hypervalent iodonium salts, producing versatile conjugates that can undergo further bioorthogonal modifications. This powerful strategy proceeds with high efficiency and chemoselectivity across a range of small proteins and polypeptides. In this work, we describe the …

    cambridge Repository record for Hypervalent iodine reagents for protein functionalisation (opens in a new tab)

  5. ΜΕΛΕΤΗ ΑΝΤΙΔΡΑΣΕΩΝ ΔΙΑΡΥΛΟΙΩΔΩΝΙΑΚΩΝ ΚΑΙ ΦΑΙΝΥΛΟ(Β-ΑΡΥΛΟΑΙΘΙΝΥΛΟ) ΙΩΔΩΝΙΑΚΩΝ ΑΛΑΤΩΝ

    … DECOMPOSITION. PHENYL(ARYLETHYNYL) IODONIUM SALTS REACT AS 1,3-DIPOLAROPHILES WITH NITRILOXIDES TO AFFORD PHENYL (SUBSTITUTED ISOXAZOLYL) IODONIUM SALTS. THE CHEMICAL PROPERTIES OF THE CYCLOADDITION PRODUCTS IS BRIEFLY EXAMINED. PHENYL (ARYLETHYNYL) IODONIUM SALTS REACT ALSO WITH NITRONES BUT …

    greece Repository record for ΜΕΛΕΤΗ ΑΝΤΙΔΡΑΣΕΩΝ ΔΙΑΡΥΛΟΙΩΔΩΝΙΑΚΩΝ ΚΑΙ ΦΑΙΝΥΛΟ(Β-ΑΡΥΛΟΑΙΘΙΝΥΛΟ) ΙΩΔΩΝΙΑΚΩΝ ΑΛΑΤΩΝ (opens in a new tab)