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Showing 1 to 2 of 2 for “"Cyclopropyl ketones"”.
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Rearrangements of Radical Anions Generated from Cyclopropyl Ketones
Cyclopropyl-containing substrates have been frequently utilized as "probes" for the detection of SET pathways in organic and biorganic systems. These reactions are based on the cyclorpropylcarbinyl → homoallyl rearrangement, which is fast and essentially irreversible. The implicit assumption in …
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Radical anion rearrangements. aryl cyclopropyl ketyl anions
Aryl cyclopropyl ketones have often been employed as diagnostic probes for single electron transfer (SET) in organic chemical reactions. The implicit assumption in such studies is that the formation of rearranged product(s) can be ascribed to the intermediacy of a ketyl anion. Through a detailed …