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Showing 1 to 2 of 2 for “"Cyclophan"”.
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The synthesis and chemistry of the cyclophanenes and their metal complexes
A new synthetic route to cyclophanenes 56, starting from an appropriate 2,6-dihalogen-substituted toluene via monothiacyclophanes as intermediate compounds, was developed. By this method, anti-5,8,13-16-tetramethyl [2,2] (1,3)cyclophan-1-ene, 56b, and anti-4,6,8,12,14,16-hexa-methyl [2,2] …
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Redox properties of Bis-Triarylamines and ligand properties of Thianthrenophane
… in a symmetry broken CT state. The [2.2]paracyclophane bridged dimer is an example for a weakly coupled system, because the spectroscopic behavior is very similar to the corresponding p xylene monomer. In contrast, anthracene as well as p-xylene bridges mediate a stronger coupling and reveal …