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Showing 1 to 2 of 2 for “"Cumulenes."”.
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Substituent Effects: A Computational Study on Stabilities of Cumulenes and Low Barrier Hydrogen Bonds
The effect of substituents on the stabilities of cumulenes-ketenes, allenes, diazomethanes and isocyanates and related systems-alkynes, nitriles and nitrile oxides is studied using the density functional theory (B3LYP, SVWN and BP86) and ab initio (HF, MP2) calculations at the 6-31G* basis set …
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Preparation and reactions of some organic derivatives of manganese carbonyl compounds
… with the electronically and structurally related cumulenes, N-sulfinylaniline (PhN=S=O), N-sulfinylbenzenesulfonamide (PhS(O)₂N=S=O) and the disulfonylsulfodiimide [PhS(O)₂N]₂S have been investigated. SO₂ inserts efficiently into the Mn-Cₐᵣᵧₗ bond of a range of orthomanganated ketones, to give the …