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Showing 1 to 2 of 2 for “"Csp3 coupling"”.
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STEREOSPECIFIC SUZUKI-MIYAURA CROSS-COUPLING OF CHIRAL BENZYLIC BORONIC ESTERS AND VINYL BROMIDES
The Suzuki-Miyaura cross-coupling reaction is a powerful method for the construction of carbon-carbon bonds in academia and industry. Despite extensive research in this area and the significance of the reaction, it is most often employed to prepare flat, Csp2-Csp2 bonds between two aryl groups. …
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Ligand design principles for perfecting stereoretention in Suzuki-Miyaura cross-coupling of unactivated CSP3 boronic acids
… blocks. Iteration of metal-mediated cross-coupling reactions represents a promising direction, and such an approach has already been automated and used to make many different small molecules. Still, the lack of methods for Csp3 coupling dramatically limits the scope of building block-based …