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Showing 1 to 5 of 5 for “"Corroles"”.
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Selective Oxidations by Iron(III) Porphyrins and Iron(III) Corroles
<p>The selective oxidation of organic compounds represents a leading technology for chemical industries. They are used in chemical synthesis in the pharmaceutical and petrochemicals industries, and possible the decontamination of harmful substances. However, oxidations reaction are among the most …
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Electrochemistry, Acid-base Properties and Spectroelectrochemistry of Porphyrins, Corroles, and Related Molecules
… and acid-base properties of porphyrins, corroles and related molecules in non-aqueous media. The acid-base properties monitored by electrochemical methods and spectroscopy were examined as to four types of free-base porphyrins (with meso-substituents, with β-substituents, with negatively …
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Electrochemical and Spectroelectrochemical Studies of Complexes with Multiple Redox Centers
… electroactive compounds included: (i) free base corroles with nitro substituents at the β-pyrrole positions, (ii) β-nitro substituted iron corroles, (iii) bis-[PcRu(CO)][Ru2(ap)4(C≡CC5H4N)2]: a tetraruthenium complex containing two ruthenium(II) phthalocyanines and one metal-metal bonded …
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Selective Oxidations by Metalloporphyrins and Metallocorroles
… to sulfoxides was developed by using iron(III) corroles (4) and PhI(OAc)<sub>2</sub> as mild oxygen source. Allylic thioanisoles and hydroxy sulfides could be successfully oxidized with good conversions and excellent selectivities within short time period. A significant accelerating effect on …
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Synthesis of symmetric and asymmetric water-soluble porphyrin derivatives
… aldehydes also afforded novel metallo-butanocorroles and metallo-benzocorrole. The structures of these compounds are also analysed using MS (MALDI), NMR and X-Ray crystallography.