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Showing 1 to 5 of 5 for “"Coordination Cage"”.
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Coordination Cages: Beyond The Solution State
Metal-organic coordination cages can be assembled from simple building blocks to form a wide range of structure types such as Platonic and Archimedean solids. Such architectures are able to encapsulate a diverse array of molecular guests in the solution state, from both organic and aqueous media. …
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Synthesis and single-molecule force spectroscopy of supramolecular capsules
… In the first part, large supramolecular coordination cages have been prepared by metal-directed self-assembly of functionalized cavitands. The synthesis of the hexameric coordination cage demonstrates, that functionalized cavitands can be used to obtain large metallosupramolecular …
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Coordination Cages as a Scaffold for Permanently Porous Liquids
… separations. We present the first adaptation of coordination cages into porous liquids by functionalizing a series coordination cages of different sizes and structures with alkylimidazolium and PEG-imidazolium moieties. The alkylimidazolium-functionalized cages showed increased solubility in …
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Self-Assembly of Enantiopure Subcomponents into Functional Metal–Organic Cages
Metal–organic cages possessing enclosed cavities have been shown to bind guest molecules selectively and mediate catalysis with improved reactivity and selectivity, among other applications. However, the use of enantiopure metal–organic cages for enantioselective applications has been limited both …
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Stimuli-Induced Structural Transformations of Metal–Organic Cages
… Inspired by these systems, metal–organic cages (MOCs) have emerged as versatile synthetic platforms capable of undergoing controlled transformations in response to diverse stimuli. Studying the structural responsiveness of MOCs not only deepens our understanding of dynamic self-assembly …