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Showing 1 to 3 of 3 for “"Competition Kinetics."”.
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Radical additions of hydrocarbons, ethers and acetals to alkenes via allyl transfer reaction: A new chain reaction for C-H bond functionalization
… were performed using laser flash photolysis and competition kinetics. These experiments helped us to measure the reactivity and selectivity of PINO as a chain carrier in comparison with Br. Additionally, a new competition experiment was designed to study the relative rate constant for the …
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A Radical Approach to Syntheses and Mechanisms
… Chapter 2 discusses the use of direct ultrafast kinetics techniques for investigation of crucially important enzymatic systems; while Chapter 3 demonstrates the value of indirect competition kinetics techniques for development of synthetic methodologies for commercially valuable classes of …
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Photophysics and photochemistry of natural waters with emphasis on radical probe development and application
… that were successfully trapped by 3-amp. Competition kinetics experiments with dimethyl sulfoxide resulted in a natural scavenger rate constant that matched previous literature results for coastal seawater. As expected, the addition of formate resulted in decreases, and the addition of …