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Showing 1 to 3 of 3 for “"Chimonanthine"”.
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The development of new synthetic strategies and methodologies for complex alkaloid total synthesis : a concise synthesis of (+)-chimonanthine, (+)-WIN 64821, (-)-ditryptophenaline and related alkaloids
… Alkaloids. A Concise Total Synthesis of (+)-Chimonanthine, (+)-Folicanthine and (-)Calycanthine. An efficient and convergent strategy for the synthesis of dimeric hexahydropyrroloindole alkaloids is described. The simultaneous formation of the vicinal quaternary stereocenters using a …
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METHODOLOGY DEVELOPMENT OF N-SULFINYL METALLOENAMINES AND ASYMMETRIC TOTAL SYNTHESIS OF (+)-EPIIBOGAMINE
… the total syntheses of (+)-epiibogamine and (+)-chimonanthine is described. The vinylogous aldol reaction of N-sulfinyl metallodienamines was first reported in 2017 in the total synthesis of (−)-albocycline. However, the diastereoselectivity of this reaction was found to be incorrectly reported. …
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NATURAL PRODUCT INSPIRED METHODOLOGIES: ADVANCES IN DIASTEREOSELECTIVE N-SULFINYL IMINE AND TRIFLUOROPYRUVIC ACID REACTIONS
… with N-sulfinyl imine for the synthesis of (+)-chimonanthine. At the beginning of my fourth year I Joined the Kim lab, where I developed photoredox catalyzed process to synthesize y-lactones. These motifs are found in various natural products and require multistep to access. I developed a method …