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Showing 1 to 2 of 2 for “"Chain melting"”.
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Critical size for bulk-to-discrete transition and segment-induced size effect melting of 2D aliphatic layers
… (AgSCn), which consists of uniform alkyl chains with spatially discrete interfaces and 2D Ag-S slabs. Two novel synthesis methods are complementarily combined to obtain AgSCn lamellar crystals with variable number of layers (m=1-4 and >10) and variable chain lengths (n=1-16). The vapor …
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Understanding correlations between secondary relaxations and thermal behaviour of biologically relevant molecules
… events detected via DSC and TGA. The carbon chain length between the amino and the carboxyl moiety is found to be a key contributor to solid-state molecular mobility. Molecular relaxation frequency was found to correlate to thermal stability of the materials investigated i.e. the lower the …