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Showing 1 to 3 of 3 for “"Catecholborane"”.
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Metal-catalyzed reactions.
… in which the amide was reacting with the catecholborane resulting in hydroboration occurring without added metal catalysts. Furthermore, catalytic amounts of simple amides, such as dimethylacetamide, could be added to catecholborane to form an active hydroboration reagent. A range of …
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Catalytic hydroboration: a study of model hydridoiridium and hydridorhodium boron complexes
… of the B-H bond in (1,2-phenylenedioxy) borane (catecholborane) to (Me₃P)₃Ir(Cl)(H) (BO₂C₆H₄ (<B>II</B>) produces <i>mer</i>-(Me₃P}₃Ir(Cl)(H)(B0₂C₆H₄) (<B>II</B>), which was characterized by ¹H NMR spectroscopy and single crystal X-ray diffraction. Compound <B>II</B> reacted with alkynes to form …
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Reactivity of a Low Valent Gallium Compound
… 1,3-addition reaction with phenylsilane and catecholborane forming gallium hydrazonides. Its reaction with diborane resulted in the formal nitrene insertion into the B-B bond to produce a gallium diborylamide. DFT calculations revealed intermediate gallium alkylidene formation from the …