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Showing 1 to 2 of 2 for “"Catalytic Asymmetric Reactions"”.
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Experimental and Computational Studies on Copper and Hydrobenzoin Derivatives in Catalytic Asymmetric Reactions
The use of theory to understand and facilitate catalytic enantioselective organic transformations involving copper and hydrobenzoin derivatives is reported. Section A details the use of theory to predict, facilitate, and understand a copper promoted amino oxygenation reaction reported by Chemler et …
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The modification of brucine derivatives as chiral ligands and its application in the asymmetric synthesis
… MBH reaction of alkyl vinyl ketone. In addition, asymmetric MBH reactions of alkyl vinyl ketones with aldehydes were investigated using a dual catalysis of brucine <em>N</em>-oxide and proline. In this dual catalyst system, proline was found to form iminium intermediates with electron-deficient …