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Showing 1 to 13 of 13 for “"Carboranes"”.
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Arsacarboranes: A New Series of Heteroatom Carboranes
Made available in DSpace on 2014-12-09T17:36:30Z (GMT). No. of bitstreams: 1 7013259.pdf: 2030856 bytes, checksum: 03e8b0265fd70ce49926e11be4c2276a (MD5) Previous issue date: 1969
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Some Chemistry of Carboranes Containing Group Five Elements
Made available in DSpace on 2014-12-09T17:36:39Z (GMT). No. of bitstreams: 1 7013487.pdf: 2149137 bytes, checksum: febdc2dc78375254702426389eefe8d4 (MD5) Previous issue date: 1969
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Plasma-enhanced molecular layer deposition (PEMLD) of boron carbide dielectrics from carboranes for interconnect and patterning applications
… (PEMLD) process for boron carbide from carboranes. This novel method will allow for the deposition of thin films of boron carbide with molecular-level control. Boron carbide, which lies outside the silicon class of materials, has appealing chemical, mechanical, electrical, dielectric, …
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The Development of New Routes to Half-Sandwich Metallatricarbadecaborane Complexes, Triflate-Functionalized Polyboranes and Carboranes, and Ammonia Borane Hydrogen Release
… first pathways to B-triflate-substituted ortho-carboranes and decaborates. Chapter 3 reports that the metal-catalyzed hydrogen release from ammonia borane (AB) in an ionic liquid produces a significant increase in initial H2-release. However, the metal-catalysts affect only the rate of loss of …
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Functionalized nido-C4B2, closo-C2B5 and -C2B10 Carboranes, and Reactivity Studies on Electron-Poor 2,3-Dihydro-1,3-diborolyl Complexes of Ruthenium
The dissertation describes work on organoborane/carborane compounds (Chapters 3.1, 3.2, 3.3, 3.5), on the reactivity of 2,3-dihydro-1,3-diborolyl complexes of ruthenium (3.4), and on aminoborane derivatives (3.6). In Chapter 3.1, a one-pot synthesis of …
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The syntheses and reactions of thallium and dithallium dicarbollides
… some interesting thallium-containing heterocarboranes. The major pyrolysis products are thallium metal and TlR¹R²C₂B₉H₁₀. Hydrogen and the corresponding closo-carboranes, R¹R²C₂B₉H₉, were produced as minor products. The reactions of Tl₂R¹R²C₂B₉H₁₀ compounds with weak organic acids yielded …
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Developing Stimulated Raman Spectroscopic Techniques For Imaging Below the Optical Diffraction Limit
… we demonstrate the use of a new Raman tag using carboranes. By scanning a thin film of a carborane-terminated poly(N-isopropylacrylamide) (pNIPAAm), we show that their high density of B-H bonds and their unique vibrational frequency in the cell silent region make carboranes useful Raman imaging …
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The analysis of rocket propellants by carbon-13 NMR
… ingredients (aliphatic nitrate esters, carboranes, plasticizers and stabilizers) are reported.
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Synthesis and reactivity of ortho-carborane functionalized boron species.
… substituted boron on complexes bearing two ortho-carboranes that are labile and can activate strong bonds. The experimental scales reveal that the synthesized compounds are strong Lewis acids that are supported by DFT calculations indicate they are Lewis superacids. Overall, this work advances the …
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Polystyrene coated iron-platinum drug delivery platforms for theranostics
… have been developed through the inclusion of carboranes.7,8 These drugs have shown increased potency and antiproliferative activity against cancer cells in vitro through the use of various cell culture assays.9/11 The inhibitory concentrations on various cells lines were reported through the …
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Synthesis, characterization and biological studies of carboranyl-porphyrin bioconjugates for treatment of brain tumors
<p>Chapter 1 gives a brief introduction to brain tumors, approaches to deliver drug across the blood brain barrier (BBB), boron neutron capture therapy (BNCT) for brain tumors, application of carboranyl derivatives in attempt to treat brain tumors using BNCT. Chapter 2 involves synthesis, …