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Showing 1 to 2 of 2 for “"Carbon acidity"”.
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Pushing the Limits of the Lithium Indicator Carbon Acidity Scale Using Cyclopentadiene Chemistry and 19F NMR Spectrometry
… type of ordinary chemical bond and studying carbon acidity will help us understand and predict the reactivity of organic compounds. Carbon acidities are ranked using acidity scales. One of the most prominent is the Streitwieser Lithium Indicator (SLI) scale. The term "indicator scale" implies …
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Challenging the Limitations of the Streitwieser Lithium Indicator Acidity Scale with Cyclopentadiene Derivatives
… linking the Streitwieser Lithium Indicator (SLI) acidity scale to the aqueous Bronsted-Lowry scale to give true pKa values to carbon acids measured on the SLI scale. To achieve this goal, we needed at least one carbon acid that is both water- and THF-soluble and that has an acidity appropriate to …