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Showing 1 to 2 of 2 for “"Carbohalogenation"”.
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Rhodium-Catalyzed Asymmetric Ring Opening of Oxabicyclic Alkenes and Palladium-Catalyzed Carbon-Halogen Bond Forming Reactions
… palladium(0) catalysis via the intramolecular carbohalogenation and chlorocarbamoylation of alkynes. During our investigations, we discovered that the steric bulk of both the substrate and the phosphine ligand play an important role in promoting the desired reactivity. Mechanistic insight has …
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Stereoselective Heterocycle Synthesis via Alkene Difunctionalization: Bulky Phosphine Ligands Enable Pd-Catalyzed Arylhalogenation, Arylcyanation and Diarylation
Due to the ubiquity of heterocyclic scaffolds in naturally occurring compounds and pharmaceutical drugs, an important longterm goal in organic chemistry has been developing new heterocycle syntheses. Research in the Lautens group has led to many advances in this field, specifically using Rh and Pd …