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Showing 1 to 2 of 2 for “"Carbastannatranes"”.
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The Modified Stereospecific Stille Reaction: Palladium-Catalyzed Cross-Coupling Reactions Involving Secondary and Tertiary Alkyl Carbastannatranes
… cross-coupling reactions with secondary alkylcarbastannatranes with exceptional stereofidelity and with net retention of absolute configuration. Because the stereochemistry of the resulting products is entirely reagent-controlled, this process may be viewed as a general, alternative approach …
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Synthesis of Biologically Active Tropolones and Stereochemically Rich Compounds via Cross-Coupling Reactions
… using configurationally stable enantioenriched carbastannatranes, as the organotin coupling partner, has been realized with control over retention or inversion of stereochemistry. This is accomplished using palladium catalysis in combination with an electron deficient Buchwald type ligand and …