Global ETD Search

EXPLORING CO2 FUCTIONALIZATION WITH D6 COMPLEXES AND MATERIALS

Cypher, Sabrine, Marie2023

Carbon dioxide (CO2), a potent greenhouse gas, is produced as a waste in many industrial processes, yet few processes incorporate CO2 as a C1 feedstock. To address this imbalance, we explore additional avenues for the use of CO2 to produce industrially relevant commodity chemicals via d6 transition …

penn Repository record for EXPLORING CO2 FUCTIONALIZATION WITH D6 COMPLEXES AND MATERIALS (opens in a new tab)

Reaktivität von CO2 gegenüber Si-N-Bindungen

Herbig, MarcusTU Bergakademie Freiberg

Um die Insertionsreaktionen von CO2 in Si-N-Bidungen genauer zu erforschen wurden 122 Silicium-Verbindungen synthetisiert -- davon 56 erstmalig -- und umfassend strukturell charakterisiert. Wichtige Hinweise auf die Voraussetzungen für das Ablaufen der Insertion konnten aus den qualitativen und …

qucosa-diss

Controlling the reactivity of Mo(III) with di- and tri-atomic molecules via sterically demanding ligands

Cherry, John-Paul F. (John-Paul Francis), 1971-Massachusetts Institute of Technology2002

… shown to have a rather robust bond into which CO2 insertion was not possible. However, the reactivity derived from within a series of carboxydiazenido complexes, (Ar[tBu]N)3MoN2CO2R was strikingly different. The molecule fell apart upon deprotecting the CO2 fragment by removing an alkyl group, …

mit Repository record for Controlling the reactivity of Mo(III) with di- and tri-atomic molecules via sterically demanding ligands (opens in a new tab)

Green and sustainable polymers: high-value aliphatic polycarbonates from CO2 and epoxides

Haas, GerhardUniversität Ulm

ulm-diss Repository record for Green and sustainable polymers: high-value aliphatic polycarbonates from CO2 and epoxides (opens in a new tab)

Part I: The synthesis of chenodeoxycholic acid derived macrocyles and cage compounds. Part II. Sonogashira coupling for the synthesis of well-defined π-conjugated arylene ethynylene oligomers as blue-light-emitting materials

Bai, XinyanUniversity of Missouri--Kansas City2012

… A novel CDCA derivative with an ambient CO2 insertion to 7α-side chain has been serendipitously discovered. It is the first time that CO2 has been directly introduced to the steroid molecules by organic synthetic method. It also provides a potential methodology to synthesize 14C labeled …

umkc Repository record for Part I: The synthesis of chenodeoxycholic acid derived macrocyles and cage compounds. Part II. Sonogashira coupling for the synthesis of well-defined π-conjugated arylene ethynylene oligomers as blue-light-emitting materials (opens in a new tab)