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Showing 1 to 5 of 5 for “"CO2 binding"”.
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Binding, activation, and transformation of carbon dioxide mediated by anionic metal complexes
… from the reaction of [Na][NNb(N[Bu]Ar) 3] with CO2 is presented. Its solid-state structure in the form of the ionpair [(12-crown-4) 2Na][O2CNNb(N['Bu]Ar) 3] has been determined. Reaction of the niobium carbamate complex with organic acid anhydrides results in the production of five-coordinate …
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Structural Investigation On The Thermal Degradation Of Aqueous Amines In Post-Combustion Co2 Capture
… temperature is with the elevating levels of CO2 in the atmosphere. Combustion of fossil fuels in power plants is a leading contributor to the elevated anthropogenic CO2 concentration. To help alleviate this issue, the investigation of aqueous amines being implemented for the capture of CO2 in …
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Electrochemical CO2 reduction on Cucurbit[n]uril modified Gold
… from slow reaction kinetics, low solubility of CO2 and hydrogen formation as a competing side reaction. In general, rational control over reaction intermediates via (de-)stabilising interactions remains a major challenge in electrocatalysis more broadly. In this thesis, gold surfaces were …
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Structural and functional studies of phosphoenolpyruvate carboxykinase
… and ATP into phosphoenolpyruvate, ADP and CO2. PCK is made up of about 500 to 600 amino acid residues and is divided into two roughly equal domains. Upon binding of substrates, the two domains of PCK move towards each other. PCK is well known for its role in gluconeogenesis but in some …
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Investigations of Electron Transport Properties in Metal-Organic Frameworks for Catalytic Applications
… in separation of gaseous mixtures, such as CO2/N2 from combustion power plants. To investigate the selective adsorption properties, we performed gas sorption measurements on bulk MOF materials to determine their affinity toward CO2. Two Zn-based MOFs containing 2,5-pyridine dicarboxylate …