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Showing 1 to 1 of 1 for “"C-F bond, FLP, Wittig, Cross-coupling, Lewis acid, Lewis base"”.
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FRUSTRATED LEWIS PAIR-MEDIATED SELECTIVE C–F BOND ACTIVATION AND SUBSEQUENT POST-FUNCTIONALIZATION OF POLYFLUOROALKANES
… suffer from ‘over-reaction’, where multiple C-F bonds are uncontrollably functionalized. We have developed a Frustrated Lewis Pair (FLP) mediated C-F bond activation which allows selective monodefluorination of polyfluoroalkanes via base capture of intermediate fluorocarbocations. This …