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Showing 1 to 3 of 3 for “"Bulky Ligands"”.
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Structural Analysis Of Bulky Thiolate-Protected Gold Nanomolecules
… most commonly, straight-chain organic thiolate ligands for which the sulfhydryl `head' group is bound to a primary carbon atom. The primary connectivity of these sulfur atoms, such as for the case of n-hexanethiol and phenylethanethiol, allows for even packing, and the relative ease of formation …
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The synthesis of kinetically stabilised heavy group 13 hydride complexes
… discussed, and is the development of stabilising ligands. Chapter Two discusses the variability in the stereoelectronic character of stabilising ligands and describes the development of a number of probes to quantify the stereoelectronic character of monoanionic bidentate N,Nʹ-ligands. This …
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Dendritic rhodium catalyst precursors for the hydroformylation of olefins
… reaction conditions. The strategy of appending bulky ligands has often been employed to enhance catalytic activity and selectivity. Dendritic wedges are promising to the field of catalysis, as one branch may possess multiple surface terminal groups and the other branch may consist of a …