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Showing 1 to 2 of 2 for “"Baylis-Hillman Reaktion"”.
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Katalytische Festphasensynthese in Gegenwart von komprimiertem Kohlendioxid
… reactions with gaseous substrates while the Baylis-Hillman reaction (BHR) was chosen because of its high negative reaction volume. For all reactions fast and effective coupling- and cleavage conditions were found. Reaction conditions were optimized allowing for comparing the reactions in …
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Chirale ionische Flüssigkeiten in der homogenen Katalyse
… of the anionchiral IL on the organocatalyzed Aza-Baylis-Hillman reaction was analyzed. Addition of the chiral IL led to a loss in selectivity and increased formation of a byproduct: through the hydrolysis of the substrate the corresponding aldehyde was formed. With low concentrations of the ioniq …