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Showing 1 to 2 of 2 for “"Azaenolate"”.
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Asymmetric α-Alkylation of Acyclic Ketones Utilizing Chiral Nonracemic N-Amino Cyclic Carbamate Hydrazones
Asymmetric variants of ketone α-alkylation are highly important given that numerous natural products, drugs, and related compounds exist as α-functionalized ketone or derivatives thereof. A method for asymmetric α-alkylation of ketones using N-Amino cyclic carbamate (ACC) chiral auxiliaries is …
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New methods for the asymmetric synthesis of α-alkylated ketones and 1,3-amino alcohols
… of an asymmetric alkylation of non-chiral azaenolates. Enantiomeric ratios up to 83 : 17 are observed. Chapter 4 introduces the first aldol-Tishchenko reaction of an imine derivative for the preparation of 1,3-aminoalcohol precursors. 1,3-Aminoalcohols can be synthesised via indirect routes …