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Showing 1 to 20 of 46 for “"Au(111)"”.

  1. Surface Coverage and Structure of Catalytic Monolayers on Au(111) Electrodes

    … inhibition, indicate that it binds to the Au(111) electrode throughout the double layer potential region. At positive potentials, it delays the onset of gold oxide formation. At extreme negative electrode potentials, the anion desorbs from the surface, confirming activity observed with SPM. …

    uiuc Repository record for Surface Coverage and Structure of Catalytic Monolayers on Au(111) Electrodes (opens in a new tab)

  2. Nucleation and Growth of Order in Cu(3)Au (111) Films

    During epitaxial growth of (111) face-centered cubic crystal films, such as disordered $\rm Cu\sb3Au,$ there are two possible ways that successive layers can be laid down, leading to two types of stacking domains. However, a small vicinal miscut $(0.5\sp\circ {-}1\sp\circ )$ of the crystal surface …

    uiuc Repository record for Nucleation and Growth of Order in Cu(3)Au (111) Films (opens in a new tab)

  3. Molecular-level study of N-heterocyclic carbenes: Binding modes and self-assembly on Au(111)

    … to study the self-assembly of NHCiPr on Au(111). The isopropyl wing-tip groups of NHCiPr play an important role in the self-assembly process. They are responsible for steric interactions with the surface and for stabilizing an ordered zig-zag lattice via intermolecular CH-pi non-covalent …

    queens Repository record for Molecular-level study of N-heterocyclic carbenes: Binding modes and self-assembly on Au(111) (opens in a new tab)

  4. Probing the Properties of the Molecular Adlayers on Metal Substrates: Scanning Tunneling Microscopy Study of Amine Adsorption on Au(111) and Graphene Nanoislands on Co(0001)

    … 1,4-benzenediamine (BDA), on the reconstructed Au(111) surface, chosen for its potential application as a molecular electronic device. The molecules were deposited in the gas phase onto the substrate in the vacuum chamber. Five different patterns of BDA molecules on the surface at different …

    columbia-diss Repository record for Probing the Properties of the Molecular Adlayers on Metal Substrates: Scanning Tunneling Microscopy Study of Amine Adsorption on Au(111) and Graphene Nanoislands on Co(0001) (opens in a new tab)

  5. Nanotemplate creation and self-assembly on the (111) surface of gold

    … processes of ordered growth and self-assembly on Au(111). I did a combined AES/STM study of the formation of ordered networks of Co islands on Au(111) and obtained the conditions for growing uniform, bi-layer Co-terminated clusters. In another STM study I obtained novel results which reveal the …

    unh-thes Repository record for Nanotemplate creation and self-assembly on the (111) surface of gold (opens in a new tab)

  6. The Structure and Activity of Admetal-Modified Single Crystal Platinum and Gold Electrodes

    … of the admetal deposits (Ru or Os) on Pt(111) and Au(111) were also compared to better understand the spontaneous deposition process. X-ray photoelectron spectroscopy (XPS) was used to provide supporting information for Pt(111)/Os. Repeating the spontaneous deposition process for low-index …

    uiuc Repository record for The Structure and Activity of Admetal-Modified Single Crystal Platinum and Gold Electrodes (opens in a new tab)

  7. Epitaxial nanolayers of large organic molecules

    … Wachstum von großen organischen Molekülen auf kristallinen Substraten mit Hilfe der Quaterrylenderivate QT, QTCDI und QTCMI untersucht. Um derartige Schichten herstellen und charakterisieren zu können, wurde eine Organische Molekularstrahlepitaxy (OMBE)-Anlage aufgebaut. Allerdings stellt …

    qucosa-diss

  8. In situ studies of the binding and reactivity of small molecules at metal electrode surfaces

    … studies of the behavior of aromatic molecules on Au(111) single crystal electrode surfaces. In the first study, the initial stages of the binding and oxidation of phenol at high pH were addressed. Phenoxide binds to the electrode surface through the oxygen atom and is tilted away from the surface …

    uiuc Repository record for In situ studies of the binding and reactivity of small molecules at metal electrode surfaces (opens in a new tab)

  9. Interfacial Electronic Structure of Dipolar Vanadyl Naphthalocyanine Thin Films

    … highly ordered pyrolytic graphite (HOPG) and Au(111).The substrate of HOPG is a surface which does not possess reactive dangling bonds and the electron density close to the Fermi edge is very low, permitting high resolution spectroscopic band analysis of VONc and revealing subtle changes to …

    arizona-thes Repository record for Interfacial Electronic Structure of Dipolar Vanadyl Naphthalocyanine Thin Films (opens in a new tab)

  10. Modeling the self-assembly of functionalized fullerenes on solid surfaces using Monte Carlo simulations

    … Clusters of 40 molecules are simulated on the Au(111) substrate at different temperatures and surface coverage densities. Fullerenes and S atoms are found to compete for Au(111) surface sites, and this competition prevents self-assembly of highly ordered monolayers.</p><p>Next, we investigate …

    unh-thes Repository record for Modeling the self-assembly of functionalized fullerenes on solid surfaces using Monte Carlo simulations (opens in a new tab)

  11. A variable temperature scanning tunneling microscopy study of organizing C60 molecules on nanostructured gold surface

    … of C\(_{60}\) molecular nanostructures on the Au (111) surface are studied under various conditions using variable temperature UHV STM. At room temperature, the C\(_{60}\)/Au interface exhibits rich features observed in the STM images, for instance the lifting of the reconstruction and the …

    birmingham Repository record for A variable temperature scanning tunneling microscopy study of organizing C60 molecules on nanostructured gold surface (opens in a new tab)

  12. Electronic Coupling Effects and Charge Transfer between Organic Molecules and Metal Surfaces

    … obtained for a quaterrylene (QT) monolayer on Au(111), the spectral shape resembles that of isolated molecules when QT is grown on graphite. We even achieve an efficient electronic decoupling from the subjacent Au(111) by inserting an atomically thin organic spacer layer consisting of …

    qucosa-diss

  13. Structure and Evolution of Intermetallic and Metallic Overlayers Onfcc(111) Metal Surfaces

    … underpotential deposition (UPD) of cadmium onto Au(111) in aqueous solution was studied with STM and cyclic voltammetry. This system resulted in three linear overlayer structures which do not directly reflect the substrate symmetry. This result is in direct contrast to the majority of the UPD …

    uiuc Repository record for Structure and Evolution of Intermetallic and Metallic Overlayers Onfcc(111) Metal Surfaces (opens in a new tab)

  14. Investigations of Structure / Property Interrelationships of Organic Thin Films Using Scanning Probe Microscopy and Nanolithography

    … (DPP) on Au(111) were done using SPL methods of nanoshaving and nanografting. Automated computer designs were developed for nanofabrication to provide local characterizations of the thickness of DPP films and nanostructures. Nanolithography was accomplished …

    lsu-thes Repository record for Investigations of Structure / Property Interrelationships of Organic Thin Films Using Scanning Probe Microscopy and Nanolithography (opens in a new tab)

  15. In Situ Structural Study of Underpotential Deposition and Electrocatalysis on Gold(111) Electrodes

    … Ag, and Hg underpotential deposition (UPD) on Au(111) electrodes. The application of the atomic force microscope (AFM), the scanning tunneling microscope (STM), and the surface x-ray scattering (SXS) to these UPD studies has provided in situ measurements from which we investigate factors that …

    uiuc Repository record for In Situ Structural Study of Underpotential Deposition and Electrocatalysis on Gold(111) Electrodes (opens in a new tab)

  16. Von der organischen Heteroepitaxie zu organisch-organischen Heterostrukturen

    … (PTCDA) und Peri-Hexabenzocoronen (HBC) auf verschiedenen einkristallinen Oberflächen von Gold und Graphit untersucht. Zur Abscheidung der Moleküle und zur Herstellung dünner hochgeordnerter organischer Schichten wurde eine Molekularstrahlepitaxieanlage mit mehreren Kammern aufgebaut. Bei …

    qucosa-diss

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