Global ETD Search
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Showing 1 to 2 of 2 for “"Arene hydroxylation"”.
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Exploring reactivity and component interactions in Toluene/o-Xylene Monooxygenase from pseudomonas sp. OX1
… Presence of its Redox Partners. To hydroxylate arene substrates, toluene/o-xylene monooxygenase (ToMO) utilizes four protein components, a catalytic hydroxylase (ToMOH), a regulatory protein (ToMOD), a Rieske protein (ToMOC), and a reductase (ToMOF). Within ToMOH, this chemistry is achieved …
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Studies toward the synthesis of celastrol and the late-stage hydroxylation of arenes mediated by 4,5-dichlorophthaloyl peroxide
… Following our initial report describing the hydroxylation of arenes using phthaloyl peroxide, new peroxide derivatives were investigated to probe their reactivity in an effort to hydroxylate aromatics which were previously unreactive. Electronically poor to moderately rich arenes were …