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Showing 1 to 4 of 4 for “"Anion Relay Chemistry"”.
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Partnering Photochemical Protocols With Anion Relay Chemistry: Application In The Total Synthesis Of Natural Products
Anion Relay Chemistry (ARC), a multi-component union tactic, permits rapid assembly of linear and cyclic fragments. Partnering photochemical protocols with Anion Relay Chemistry can provide diverse reaction pathways and as such considerably extends this construction paradigm. The development of new …
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Anion Relay Cyclopropanation and Aryl Vinyl Cyclopropane Cope Rearrangements
Anion Relay Chemistry is a powerful tool for the rapid development of molecular complexity in an operationally simple manner. Much of the work in this field has been pioneered and developed by the Smith group, whose work has primarily focused on silicon and phosphorus Brook rearrangements to effect …
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Towards the Total Synthesis of Spirastrellolide E: Investigations into Advanced Southern Hemisphere Fragments
… fragment. Key steps involve a convergent Type I Anion Relay Chemistry (ARC) union and a gold catalyzed directed spiroketalization. Chapter 3 then revises the overall retrosynthetic analysis by proposing a novel strategy for hemisphere union, involving a cross metathesis/epoxidation/epoxide ring …
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DESIGN, SYNTHESIS, AND OPTIMIZATION OF SMALL-MOLECULE CD4 MIMETICS AS HIV-1 ENTRY INHIBITORS AND SYNTHETIC EFFORTS TOWARD THE TOTAL SYNTHESIS OF NAHUOIC ACID Cii
… side chain was assembled via Type II Anion Relay Chemistry (ARC), while the cis-decalin core was constructed through a Ti–TADDOLate-catalyzed asymmetric Diels–Alder reaction. To replace the traditional mercury-based protocol, a visible-light Eosin Y-mediated photocatalytic method was …