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Showing 1 to 7 of 7 for “"Alternating Copolymerization"”.
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Studies Related to the Alternating Copolymerization of Substituted Stilbenes
… to understand the methyl substituent effect on copolymerization rates. Methyl substituted stilbene-maleic anhydride copolymer compositions were determined by quantitative ¹³C 1D NMR. SEC measurements showed the weight average molecular weights of these copolymers vary from 3 000 to over 1 000 …
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Synthesis And Catalytic Studies Of Zinc Complexes Of Amido-Oxazolinate Ligands
… These complexes are viable initiators for alternating copolymerization of carbon dioxide (CO2) and cyclohexene oxide (CHO), yielding moderate isotactic poly(cyclohexene carbonate) (PCHC) with good to high carbonate linkage and moderate molecular weights and PDI values, depending on the …
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Synthesis and Characterization of Highly Functional Substituted Stilbene Copolymers and Semi-crystalline Poly(aryl ether sulfone)s
… rod-like copolymers have been synthesized by alternating copolymerization of N, N, Nâ , Nâ -tetraalkyl-4, 4â -diaminostilbenes (TDAS) with maleic anhydride. Dynamic light scattering, 2H solid state NMR and persistence length measurement reveal high chain rigidity of the polymer backbone. …
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Functional Polymers Containing Semi-Rigid Alternating Sequences
Alternating copolymers represent a special class of copolymers in which the two comonomers copolymerize in a regular alternating sequence along the polymer chain. Of particular interest in our group are the stilbene-maleic anhydride/maleimide alternating copolymers. These copolymers possess …
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Sterically Crowded Copolymers Based on Functionalized Stilbenes
… of the donor-acceptor comonomer pairs and the alternating copolymerization of these comonomers lead to precise control over charge density and placement of charged groups along the polymer backbone. Analogous styrenic copolymers, for direct comparison to the stilbene structures, were also …
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Z-selective olefin metathesis processes and Cis/syndioselective ROMP with high oxidation state molybdenum alkylidenes
… polymer that is syndiotactic and composed of alternating enantiomers. The cis, syndiotactic ROMP of several other racemic chiral monomers are reported, also affording structures containing a high degree of enantiomer alteration. Attempts towards the alternating copolymerization of two …
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Synthesis and Characterization of Multi-Component Polymeric Materials Prepared via Free Radical Polymerization
… Additional functionality was introduced via the copolymerization of MAH with several norbornene (Nb) derivatives that were synthesized from facile Diels-Alder cycloaddition reactions of cyclopentadiene with a-olefins containing electron withdrawing groups. Subsequent hydrolysis of the anhydride …